Tracking the Advances in the Conversion CO2 into Polymers

By
SD
Sreeparna Das
on September 20, 2021
CO2 in the air

The chemical industry’s demand for carbon continues to grow, and so does the need to lower its dependency on fossil fuels. This, coupled with the goal to achieve net-zero emissions by 2050, has accelerated feedstock innovations. Along with new generations of bio-based feedstocks and advanced recycled raw materials, the industry is actively exploring Carbon Capture and Utilization (CCU) technologies to use CO2 as a feedstock.

Some promising advances have been made in recent years, and we start to see examples of commercial products. A joint partnership between LanzaTech, Total Energies and L’Oréal recently made headlines with the development of a Cosmetic Plastic Bottle made from waste CO2!

 Cosmetic Plastic Bottle white. L’Oréal

CO2 -> Ethanol -> Ethylene -> Polyethylene -> Cosmetic Plastic Bottle. Image credit: L’Oréal

The three partners are working together to scale up the production of these sustainable plastic packaging. We’ll get to more such examples and other developments a little later in the article. But first, let’s understand a bit more about the technology.

CCUS – The Basics

Thanks to Elon Musk funding the $100M XPRIZE Carbon Removal contest, Carbon Capture, Utilization, and Storage (CCUS) technologies have taken center stage in the mainstream discussion this year.

The pathway to net-zero emissions is a complex one. While the energy sector is looking to decarbonize by moving towards renewable sources, the task is more complicated for other industries like cement, steel, mining and chemicals. With CCU technology, the flue gases emitted by these industrial plants can be used to recover CO2, which can further be upcycled into useful products. Added bonus – this also helps in lowering GHG emissions and replacing fossil-based raw materials. Win-win!

The following table illustrates the full scope of CCUS technology. And the highlighted section earmarks the scope of this article.

 

Carbon Capture, Utilization, and Storage (CCUS)Table

Upcycling CO2 into high-value chemicals and polymers

One of the initial examples of CO2 conversion into polymers that I’d come across was the one developed by the American company, Novomer. In February 2013, the company had announced its first production of 7 tons of Polypropylene Carbonate (PPC) polyol, produced using their proprietary catalyst that enabled the direct incorporation of CO2 (up to 40% by mass) into the molecular backbone of propylene oxide.

Novomer’s Converge® polyol technology was acquired by Saudi Aramco in 2016 and was made market-ready within the next two years. When incorporated into polyurethane formulations, the material demonstrated superior performance and the potential to be a sustainable alternative in coatings for household appliances, consumer and industrial adhesives, automotive and medical applications, food packaging, and more.

Currently, several conversion pathways are being explored. To achieve maximum environmental benefit, renewable energy will be needed for CO2 utilization.

Here is a comprehensive representation of all the processes and the technology readiness levels (TRLs).

 

Carbon-Dioxide-Utilisation-and-Renewable-Energy-zgkspl

Carbon dioxide conversion processes and TRLs. Image credit: nova-institute

From mattress foam and textile fibers to surfactants made from CO2, Covestro (formerly Bayer Material Science) is another pioneer in this space. Scientists and researchers from RWTH Aachen University and Covestro, as part of the “Dream Reactions” project, discovered a unique catalyst that enabled CO2 to react with high-energy substances known as epoxides without complicated side reactions. The inventors of the technology were one of the three finalists at the European Inventor Award 2021.

 

polyurethane-rigid-foam-with-co2

CO2-based Polyurethane rigid foam. Image credit: Covestro

Since 2016, Covestro has been using “Dream Resource” CO2 to produce polyols as a component for soft polyurethane foam. The polyols, marketed as cardyon®, find use in several other applications and make it possible to save up to 20 percent of fossil resources.

 

CO2 based cardyon polypol applications table

Both the examples, Saudi Aramco (Novomer) and Covestro, are classified under the chemical conversion technologies involving a chemo catalytic reaction to produce CO2-based polyols.

Next, let’s take a look at one of the leaders in biotechnological conversion. Using special microorganisms, LanzaTech converts carbon emissions (via gas fermentation) into ethanol and other chemicals. A couple of advantages to highlight here:

1. The process takes place at low temperature and low pressure, improving the overall sustainability profile of the technology.

2. Because the microorganisms can tolerate many different impurities, various sources of carbon can be used for this process without purification – from industrial emissions to syngas, from gasified agricultural or household waste (including textile waste) to atmospheric CO2.

LanzaTech’s technology is already used on a commercial scale to transform steel production exhaust gases into ethanol. And they have set up interesting partnerships across the value chain to develop new solutions. Together with Twelve, a carbon transformation company, LanzaTech plans to develop CO2Made polypropylene. And, similar to the cosmetic plastic bottle example mentioned earlier, the company has partnered with India Glycols Limited, Far Eastern New Century, and lululemon to create CO2-based polyester fabric.

CO2 -> Ethanol -> Polyester -> Fabric for apparels. Image credit: LanzaTech

CO2 -> Ethanol -> Polyester -> Fabric for apparels. Image credit: LanzaTech

 

A host of other applications will be possible in the near future thanks to LanzaTech’s latest partnership with BASF. The joint collaboration has been successful at producing n-octanol on a laboratory scale from industrial emissions (carbon monoxide and hydrogen) with the help of special bacteria. N-octanol finds use in cosmetics, among other uses.

A quick shout-out to another interesting company, Photanol that is also in the biotech space. The company has developed a unique process that harnesses cyanobacteria’s power to photosynthesize and produce key industrial compounds.

Along their journey, the company has partnered with Corbion, Nouryon and Renolit and offers a whole host of important intermediates like lactic acid, glycolic acid, ethylene, and propylene. Scale up to a commercial plant is expected in 2023.

And last but not least, let’s crank up the voltage a little bit and take a look at Avantium’s Volta Technology. You guessed it right – it is an example of the electrochemical conversion of CO2. A founding member of CO2 Value Europe, the Volta team cooperates with more than 35 partners through various EU consortia.

With expertise in Gas Diffusion Electrode (GDE) technology and paired electrolysis, their process converts CO2 into higher-value chemicals like formic acid, glyoxylic acid, and glycolic acid. They are also working on the conversion to ethylene glycol for the production of CO2-based polymers in association with researchers at the University of Amsterdam.

The pre-pilot units will be demonstrated at industrial sites this year.

 

Future outlook

So, the big question is, “Can CO2 be the raw material for chemicals and fuels in the future?” At the CO2WIN Conference held earlier this year, Prof. Eelco T. C. Vogt from the University of Utrecht presented a keynote speech, where he shared an answer to this question.

He noted that a combination of several different processes and technologies at desired scale is required to achieve this. While some of the processes are already industrially available, considerable scale-up will be required for many others.

“The main challenge lies in the capture of CO2 from air. If the refinery of the future, which consumes about 20 kton CO2 per day, would use DAC (direct air capture) for its CO2, this would require a process about 1750 times larger than the present capabilities. Capture from stationary sources would be easier and would require only a three times larger scale”, said Prof. Vogt.

He also highlighted that the electrochemical processes for the production of hydrogen and the first conversion steps of CO2 would need to be scaled up between 300 and 750 times. The more conventional chemical conversion steps, however, would already be available at the desired scale, and these include processes like:

  • Reverse water gas shift process to make CO,
  • Fischer Tropsch process to convert CO and H2 to long-chain hydrocarbons,
  • Methanol synthesis from CO and H2, and
  • Methanol to Hydrocarbons (olefins, paraffin, aromatics) process (MTH/MTO)

 

If additional raw materials are to be obtained from plastic waste or biomass, this would require a scale-up of 10 to 15 times.

The move to renewable energy will also be critical, and here, material shortage for windmills, solar panels, etc., could be a major hurdle.

Therefore, the magnitude of innovation, technology scale-up and investment required will be huge. Exponential development of technology will need to continue, and the government and industry must work together with a strong and long-term commitment.

The time to act is now!

 

*This article is the work of the guest author shown above. The guest author is solely responsible for the accuracy and the legality of their content. The content of the article and the views expressed therein are solely those of this author and do not reflect the views of Matmatch or of any present or past employers, academic institutions, professional societies, or organizations the author is currently or was previously affiliated with.

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