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Graphene monolayers, inks and powders

This content has been provided by Goodfellow

Graphene is a material consisting of a two-dimensional array of carbon atoms. The atoms are arranged in a hexagonal lattice, which resembles a honeycomb structure. Graphene can be considered as an infinitely large aromatic molecule and a single layer of the carbon graphite structure.

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The hexagonal structure of graphene. By Yikrazuul (Diskussion) [Public domain], via Wikimedia Commons. 

Discovery and synthesis

Graphene was predicted to exist as early as the 1940s, however, it was not until 2004 that monolayer graphene sheets were first synthesised. This was achieved by Andre Geim and Konstantin Novoselov, who in 2010 received the Nobel prize in physics for their discovery. Their synthesis method, termed the ‘Scotch tape method,’ was astonishingly simple. Graphene monolayers could be isolated merely by mechanical exfoliation of graphite: pulling one layer away from the bulk using adhesive tape.

In the meantime, other methods for producing graphene have been developed. These include sonication and centrifugation of graphite in a liquid to create a graphene dispersion, synthesis from sugar, called the ‘Tang-Lau method,’ reduction of silicon carbide and epitaxial growth by chemical vapour deposition (CVD).

Graphene has become a highly researched material not only for discovery of synthesis methods, but also for its impressive properties. The scientific interest in the material has grown significantly since its first isolation in 2004 and continues to do so. 

 

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The number of scientific articles published per year containing the keyword graphene. Data was collected from www.sciencedirect.com on 2nd Nov. 2018. 

General properties of graphene

Graphene is usually handled either in a dispersion, on a substrate, or as a powder of graphene oxide. Irrespective of the delivery form, the material itself has many outstanding properties including electronic, optical, thermal and mechanical properties. Many of the extraordinary properties of graphene arise from the fact that it is only one atomic layer thick.

Mechanical properties

Graphene is an extremely light material, having a planar density of 0.77 mg/m2. It also has the toughest and hardest crystal structure of all known materials. It has a tensile strength of 125 GPa and an elastic modulus of 1.1 TPa, compared to an elastic modulus of 200 GPa for the most common steel. Its breaking strength is 42 N/m; thus graphene has 100 times better mechanical strength than steel.

Optical properties

Graphene is highly transparent to visible light, with a transparency of 97.7 %. This is taken advantage of when determining the number of graphene layers, as each layer absorbs 2.3 % of light.

Electrical properties

Graphene has a very high electron mobility (2 × 105 cm2/Vs), making it the most highly conductive material at room temperature, with a conductivity of 106 S/m and a sheet resistance of 31 Ω/sq.

Graphene has a small overlap between the valence and conduction bands. Because of this, it is classed both as a semimetal and as a zero-bandgap semiconductor. The presence of a certain concentration of electrons in the conduction band and of holes in the valence band, even at absolute zero temperature (while taking into consideration its gapless electronic structure, which means that electrons can swoop through the conduction band) is the reason graphene is classified as a semi-metallic material and is the origin of its high electrical conductivity.

A single layer of graphene shows 10,000 times higher electrical conductivity than few layers graphene.

Thermal properties

Graphene has a thermal conductivity of 5300 W/mK, which is ten times the thermal conductivity of copper. When supported in an amorphous material, however, its thermal conductivity drops to around 500–600 W/mK.

Tuning of properties through functionalisation

The properties of graphene can be modified through surface functionalisation. This involves the addition of oxygen or other chemical functional groups to the monolayer. Functionalisation of graphene allows for the tuning of properties including the electrical conductivity, thermal conductivity and the ability of the monolayers to be processed in solution and prevent agglomeration. Many applications of graphene require it to be functionalised.  One of the most common chemically modified types of graphene is the graphene oxide.

Properties of graphene inks, layers and powders

Due to its two-dimensional nature, graphene can be delivered by materials supplier Goodfellow either as layers on a substrate, as a dispersion (or ink) and in the form of a graphene oxide powder.

Graphene ink, when applied to a surface results in an electrically conductive film with a sheet resistance of 15 W/sq.

Monolayer graphene can also be added to another desired substrate by transferring it from a removable polymer substrate. Monolayer graphene is fabricated via chemical vapour deposition (CVD).

 

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Easy transfer monolayer graphene transfer process from a polymer substrate to a new substrate.

 

Graphene on PET films are also available on Matmatch via Goodfellow. In this case, exceptionally high-quality monolayer graphene is grown via CVD on a 188 μm-thick PET substrate with dimensions of up to 600 mm × 500 mm. This can then also be transferred onto a new substrate. 

 

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Transmission electron microscope image of a graphene monolayer.

 

Finally, graphene can also be delivered in the form of graphene oxide powder. In this case, the powder is present in an aqueous dispersion and exhibits a mean particle size of 285 μm, a concentration of 4.0 mg/ml and a pH value of 2.20—2.50.

Graphene production

High-quality graphene is usually grown via chemical vapour deposition (CVD). This is one of the most common methods of producing high-quality graphene. In this process, gaseous reactants are introduced in a reaction chamber before reacting to form a film of the desired material on the surface of a substrate.

In the formation of graphene via CVD, this proceeds in two steps: the creation of carbon and the formation of the graphene structure.

In the first step, carbon atoms are created via pyrolysis (thermal decomposition in an inert atmosphere). This is carried out on the substrate surface to prevent the formation of carbon clusters, or soot. The substrate used is often a metal catalyst.

In the second step, a reaction occurs between the carbon atoms and the catalyst substrate which results in the formation of graphene.

Applications of graphene

Despite its relatively recent discovery, graphene has been tested extensively in fabricating many different devices, some in the early stages of development, others already on the market.

Due to its high transparency and high electrical conductivity, graphene is very attractive as a transparent conductor, which could be a less environmentally damaging replacement for indium tin oxide (ITO). Due to its flexibility, graphene can also be used in flexible displays.

The electrical properties of graphene are also taken of advantage of in creating field-effect transistors (FET), photodetectors, photovoltaics, nanoelectromechanical systems (NEMS), flexible supercapacitors and flexible lithium-ion batteries.

In addition to its electrical properties, its chemical and thermal properties lend it for use in strain sensors, gas sensors, temperature sensors, biosensors and flow sensors. Smartphone manufacturer Huawei has begun employing graphene in certain smartphones as a cooling device for integrated circuits.

The mechanical properties of graphene have also been taken advantage of to make polymer-based graphene composites and graphene fibres. It is also being incorporated into rubber to improve mechanical properties.

 

Graphene is available from Goodfellow in the form of ink, monolayer films on different substrates, functionalised graphene oxide powder and multilayer graphene powder .

 

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Article by Goodfellow

Currently celebrating 70 years of facilitating scientific innovation, Goodfellow is a leading global supplier of metals, alloys, ceramics, glasses, polymers, compounds, composites and other materials to meet the research, development and specialist production requirements of science and industry. The company has an extensive range of 70,000 catalogue products in multiple forms available off the shelf, most subject to free delivery within 48 hours and with no minimum order quantities. With over 6000 customers supported by a worldwide network of offices, agents and distributors Goodfellow also offers a comprehensive range of bespoke processing services, effectively operating as an extension of the production team in order to develop custom fabricated components in any quantity required. Our in-house team is comprised of fellow scientists and engineers with extensive knowledge of materials and processing – through their technical expertise and a supporting range of specification tools the company has built an unrivalled reputation for helping to find solutions to even the most challenging of research problems. All of our products are also underpinned by the most rigorous quality accreditations including ISO, REACH and RoHS.

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The properties of graphene include:

  • Tensile strength: 125 GPa 
  • Elastic modulus: 1.1 TPa 
  • Transparency: 97.7 %
  • Electrical conductivity: 106 S/m      
  • Thermal conductivity: 5300 W/mK